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Polymers and coatings

Calcium carbonate for plastics.

A natural aragonite ground calcium carbonate for compounders, supplied as PL-CAL to the particle specification the formulation calls for.

The filler role

The formulation sees the delivered powder, not the mineral name.

Calcium carbonate is among the most widely used mineral fillers in polymer compounding. What it does in any particular formulation — stiffness, opacity, surface finish, rheology, cost per unit volume — depends on the matrix, the loading, the particle profile and the processing, which is why a filler is qualified in the formulation rather than on a data sheet.

Composition
96.17% CaCO3

Representative analysis, ASTM C 25, Bowser-Morner report 124914A.

Surface area
> 1.7 m2/g

Keck Lab, representative analysis.

Specific gravity
2.93

Material density, for volume-loading and let-down calculations.

PL-CAL sizing
To specification

Ground and classified to the product target across mesh 20 to 325.

What a compounder specifies

Four specifications decide the powder.

Particle-size targets

Define D10, D50, D90, top size, residue and agglomerate limits from the formulation and process requirement. Particle profile is what governs dispersion, viscosity and surface finish.

Moisture and handling

Set limits for moisture, bulk handling, feeding, dust collection and storage against the production system the powder has to run through.

Surface and compatibility

State whether the formulation requires an untreated or a surface-treated product, along with resin or binder compatibility, dispersion energy and additive interactions.

Finished-property testing

Measure rheology, mechanical properties, opacity, gloss, surface finish and weathering as applicable, against the incumbent filler under the same processing conditions.

How performance gets established

In the matrix, not on a data sheet.

Mineral identity is a starting point, not a result. Aragonite and calcite are calcium-carbonate polymorphs with different crystal systems. That difference is real, and what it produces in a filled polymer still has to be established in the actual matrix.

Loading and dispersion are trial outcomes. The workable loading, the dispersion energy required and the property trade-offs come out of controlled laboratory or pilot batches run against the incumbent filler on the same equipment.

Compare like with like. Run the candidate and the incumbent under identical processing conditions and measure the properties the finished part is actually specified on.

Material comparison

Aragonite GCC, calcitic GCC and precipitated carbonate.

Decision factors for functional calcium-carbonate fillers
Decision factorAragonite GCCCalcitic GCCPrecipitated CaCO3
Origin and formNatural orthorhombic CaCO3, marine depositNatural calcitic CaCO3, quarriedManufactured calcium carbonate
Particle profileGround and classified to the product targetGround and classified to the product targetProcess-designed; grade-specific
Surface area> 1.7 m2/g representativeGrade-dependentGrade-dependent
Density (g/cm3)2.932.71 for calciteGrade- and process-dependent
Substitution decisionFormulation and process testingFormulation and process testingFormulation and process testing

Evaluation path

From particle target to production line.

01

Set the target

Provide the matrix, intended loading, particle specification, appearance targets and process constraints.

02

Compound

Run controlled laboratory or pilot batches against the incumbent filler using the same processing conditions.

03

Produce

Transfer the selected particle profile and processing conditions into the manufacturing plan.

Questions

Frequently asked questions.

What does calcium carbonate do in a plastic?

It is a mineral filler, one of the most widely used in polymer compounding. Its effect in a given formulation — on stiffness, opacity, surface finish, rheology and cost per unit volume — depends on the matrix, loading, particle profile and processing, so it is qualified by compounding trials rather than from a specification alone.

Is aragonite GCC different from calcitic GCC?

Both are natural ground calcium carbonate, but they are different mineral polymorphs: aragonite is orthorhombic at 2.93 g/cm3, calcite is trigonal at 2.71 g/cm3. The oolitic morphology also starts from rounded grains rather than angular quarried rock. What that produces in a filled system is established in the matrix.

What particle sizes are available?

PL-CAL is ground and classified to the product target, with sizing across mesh 20 to 325 depending on the application. Send the D10, D50, D90, top-size and residue targets your formulation runs to and the grade is matched against them.

Is the product surface treated?

State the requirement with the enquiry. Untreated and surface-treated needs, resin or binder compatibility, dispersion energy and additive interactions are part of the product specification discussed at the outset rather than assumed.

What loading should I use?

That is a trial outcome. Workable loading depends on the polymer, the particle profile, the processing equipment and the properties the finished part is specified on. Run controlled batches against the incumbent filler under the same conditions.

What documentation is available?

Grade specifications, particle-size data, analytical documentation and the safety data sheet, available through the contact form. The plastics industry brochure and the master technical data sheet are in the resources library.

Keep reading

Where to go next.

Discuss a particle target and formulation program.

Send the matrix, intended loading, target distribution, annual volume and destination, and AragoCor will match a grade and quote against it.